You can create an instant private chat room and select people to invite to the room in one easy step.  Instant rooms are limited to five participants.

Instant rooms are not visible on the Paltalk rooms lists. They are 'invitation only' private rooms.

select 'create private room' from the 'actions' menu on the main 'pal list window', or select 'voice and video chat' from the 'actions' menu in an IM (instant message) window if you are currently messaging a pal that you want start a private group with

select up to 4 people to invite to your private room from the list

press the 'ok' button

You will be automatically joined into the new chat room and all of your online pals that you have selected will receive an invitation to your private room.